Cellulose NP separations

The retrial on cellulose (100kD) gold separations gave similar results to the first study (results from Tecan scans):

particle salt results
5 0mM no au in filtrate, retentate concentration
15 0mM no au in filtrate
5 10mM no au in filtrate, retentate concentration
15 10mM no au in filtrate

I took the membranes and rinsed them in DI H2O.  Here are the images:

picture-23

It’s a little hard to see by the coloring of this pic, but the first two are 5 and 15 in 0mM salts, which remained white.  The second two, 5 and 15 in 10mM salts, developed a reddish color from adsorbed gold.  The last one even has a ring of purple, perhaps aggregation.  So the more shielded a material gets the better chance the gold has on getting close and being stuck to the material?

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